Publications | The Clark Lab

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PUBLICATIONS

At Marquette University

21. Sloane, S.E.; Vang, Z.P.; Nelson, G.; Qi, L.; Sonstrom, R.E.; Alansari, I.Y.; Behlow, K.; Pate, B. H.*; Neufeldt, S.R.*; Clark, J.R.* Precision Deuteration Using Cu-Catalyzed Transfer Hydrodeuteration to Access Small Molecules Deuterated at the Benzylic Position. JACS Au, 2023, ASAP.

doi.org/10.1021/jacsau.3c00053

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20. Vang, Z.P.; Sonstrom, R.E.; Scolati, H.N.; Clark, J.R.*; Pate, B. H.* Assignment of the Absolute Configuration of Molecules That are Chiral by Virtue of Deuterium Substitution Using Chiral Tag Molecular Rotational Resonance Spectroscopy. Chirality, 2023. doi.org/10.1002/chir.23596

19. Sonstrom, R.E.; Vang, Z.P.; Scolati, H.N.; Neill, J.L.; Pate, B. H.*; Clark, J.R.* Rapid Enantiomeric Excess Measurements of Enantioisotopomers by Molecular Rotational Resonance Spectroscopy. Org. Process Res. Dev. 2023. Accepted Article: doi.org/10.1021/acs.oprd.3c00028

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18. Hintzsche, S.H.; Vang, Z.P.; Rivera Torres, E.; Podoski, M.; Clark, J.R.* Highly Selective Catalytic Transfer Hydrodeuteration of Cyclic Alkenes. J. Label. Compd. Radiopharm 2023. 66, 86-94. DOI: 10.1002/jlcr.4015

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17. Mills, M.D.; Sonstrom, R.E.; Vang, Z.P.; Neill, J.L.; Scolati, H.N.; West, C.T.; Pate, B.H.*; Clark, J.R.* Enantioselective Synthesis of Enantioisotopomers with Quantitative Chiral Analysis by Chiral Tag Rotational Spectroscopy. Angew. Chem. Int. Ed. 2022. Accepted Article. DOI: 10.1002/anie.202207

16. Reyes, A.; Rivera Torres, E.; Vang, Z. P.; Clark, J. R. Highly Regioselective Copper-Catalyzed Transfer Hydrodeuteration of Unactivated Terminal Alkenes. Chemistry – A European Journal, 2022, 28 (9), e202104340. DOI: 10.1002/chem.202104340

15. Sloane, S. E.; Behlow, K. T.; Mills, M. D.; Clark, J. R. Three-Component Coupling Reactions that Generate 1,3-Dienes. Accepted for publication, 2022 (invited submission as part of the Science of Synthesis II Series).

14. Mills, M. D.; Clark, J. R. Conjugated Diene Synthesis by Rearrangement of 1,3-Dienes to 1,3-Dienes. Accepted for publication, 2022 (invited submission as part of the Science of Synthesis II Series).

13. Ide, T.; Feng, K.; Dixon, C. F.; Teng, D.; Clark, J. R.; Han, W.; Wendell, C. I.; Koch, V.; White, M. C. Late-Stage Intermolecular Allylic C–H Amination. Journal of the American Chemical Society, 2021,143 (37), 14969-14975. DOI: 10.1021/jacs.1c06335

12. Vang, Z. P.; Reyes, A.; Sonstrom, R. E.; Holdren, M. S.; Sloane, S. E.; Alansari, I. Y.; Neill, J. L.; Pate, B. H.;Clark, J. R., Copper-Catalyzed Transfer Hydrodeuteration of Aryl Alkenes with Quantitative Isotopomer Purity Analysis by Molecular Rotational Resonance Spectroscopy. Journal of the American Chemical Society, 2021,143 (20), 7707-7718. DOI: 10.1021/jacs.1c00884

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11. Vang, Z. P.; Hintzsche, S. J.; Clark, J. R., Catalytic Transfer Deuteration and Hydrodeuteration: Emerging Techniques to Selectively Transform Alkenes and Alkynes to Deuterated Alkanes. Chemistry – A European Journal, 2021, 27 (39), 9988-10000. DOI: 10.1002/chem.202100635 (Appears in Reviews Showcase - Selected by the editors as an outstanding review-type article)

10. Sloane, S. E.; Reyes, A.; Vang, Z. P.; Li, L.; Behlow, K. T.; Clark, J. R. Copper-Catalyzed Formal Transfer Hydrogenation/Deuteration of Aryl Alkynes. Organic Letters, 2020, 22 (22), 9139-9144. DOI: 10.1021/acs.orglett.0c03632

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9. Clark, J. R. Challenges Facing Young Scientists in Academia and Industry in the United States from the Lens of a Millennial Academic. Chemistry – A European Journal, 2020, 26 (68), 15759-15762. DOI: 10.1002/chem.202002665

Before Marquette University

8. Clark, J. R.; Feng, K.; Sookezian, A.; White, M. C. Manganese-Catalyzed Benzylic C(sp3)-H Amination for Late-Stage Functionalization. Nature Chemistry, 2018,10 (6), 583-591. DOI: 10.1038/s41557-018-0020-0

7. Howell, J. M.; Feng, K.; Clark, J. R.; Trzepkowski, L. J.; White, M. C. Remote Oxidation of Aliphatic C-H Bonds in Nitrogen-Containing Molecules. Journal of the American Chemical Society, 2015, 137 (46), 14590-14593. DOI: 10.1021/jacs.5b10299

6. Diver, S. T.; Clark, J. R. Ene-Yne Metathesis. Comprehensive Organic Synthesis II. 2014, 5, 1302-1356. DOI: 10.1016/B978-0-08-097742-3.00528-0

5. Clark, J. R.; Griffith, J. R.; Diver, S. T. Ruthenium Hydride Promoted Dienyl Isomerization: Access to Highly Substituted 1,3 Dienes. Journal of the American Chemical Society, 2013,135 (9), 3327-3330. DOI: 10.1021/ja4011207

4. Clark, J. R.; French, J. M.; Jecs, E.; Diver, S. T. Geminal Alkene-Alkyne Cross Metathesis Using a Relay Strategy. Organic Letters, 2012,14 (16), 4178-4181. DOI: 10.1021/ol301846q

3. Clark, J. R.; French, J. M.; Diver, S. T. Alkene Metathesis Approach to β-Unsubstituted Anti-Allylic Alcohols and Their Use in Ene-Yne Metathesis. The Journal of Organic Chemistry, 2012, 77 (3), 1599-1604. DOI: 10.1021/jo202398q

2. Clark, J. R.; Diver, S. T. Atom Economy in the Metathesis Cross-Coupling of Alkenes and Alkynes. Organic Letters, 2011,13 (11), 2896-2899. DOI: 10.1021/ol200914j

1. Clark, D. A.; Clark, J. R.; Diver, S. T. Alkenol-Alkyne Cross Metathesis. Organic Letters, 2008,10 (10), 2055-2058. DOI: 10.1021/ol800523j

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